Hot solution for hot melts

By boosting the compatibility of ingredients, naphthenic mineral oils are providing hot melt adhesive manufacturers with new and more flexible formulations

By boosting the compatibility of ingredients, naphthenic mineral oils are providing hot melt adhesive manufacturers with new and more flexible formulations.

For producers of hot melt adhesives, using metallocene-based polyolefins and resins derived from natural resources can offer significant cost-advantages. Naturally derived resins are typically less expensive to use as a tackifier than alternative hydrocarbon resins, partly because their production is based on renewable feedstock.

The challenge for manufacturers lies in incorporating these ingredients - which are typically incompatible - into hot melt formulations. The catalyst metallocene is being hailed as revolutionary for the polymer industry, but natural resins are not compatible with metallocene polyolefins (mPOs), which are also much easier to manufacture than traditional polymers.

This is where Nynas oils offer a solution. Naphthenic mineral oils show great promise as enablers of compatible mixtures, paving the way for more flexible hot melt formulations and a reduced risk exposure to feedstock shortages.

Studies carried out by Nynas demonstrate that oil with a high degree of polarity shows superior performance. Naturally based resins are polar materials, and in hot melts, the resin is typically dissolved in the oil.

However, for final formulations including polymers, peel performance testing of hot melt formulations reveals that the polarity of the oil is not the only determining factor for compatibility between natural resins and mPOs.

Investigating mineral oil, natural resin and mPO hot melt formulations

Rheology and cloud point studies show the oil/resin and resin/polymer compatibility for a variety of tackifiers and oils with different characteristics.

In Figure 1, rheological data indicates how the oil is able to render typically incompatible blends compatible.

Figure 2 illustrates that although hydrocarbon resin formulations deliver improved overall peel strength, results are comparable. Some alternative resin formulations display an improved peel strength on glass and polyethylene surfaces.

Further reading

Assisting an agent

Compatible with all sorts of rubber, naphthenic oil facilitates the dispersion of insoluble sulfur, the vulcanising agent used in the production of tyre rubber. Anna Eriksson explains how this helps improve the quality of the final rubber.

Fertile formulations

Having established in-house coating and testing of solid fertiliser, a Nynas researcher finds that naphthenic process oils offer coating formulations capable of reducing both dust and caking issues.

Perfecting purification

In a study aimed at finding the most effective purifying oil for crude titanium tetrachloride, Nynas’ researchers obtained near perfection from one mineral oil and promising results from a hybrid biogenic oil.

THERE IS MORE TO US THAN THIS

We are delighted you are interested in our products. If you have any questions about our products and services, get in touch with your local Nynas contact. Besides top quality oils, we offer a wide range of services, including rapid delivery worldwide, training, seminars and much more. All you have to do is ask.

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